Benzene in soft drinks – Flavor of the Month?

Benzene Levels in Soft Drinks Above Limit – Yahoo! News

WASHINGTON – Cancer-causing benzene has been found in soft drinks at levels above the limit considered safe for drinking water, the Food and Drug Administration acknowledged Wednesday.
Even so, the FDA still believes there are no safety concerns about benzene in soft drinks, or sodas, said Laura Tarantino, the agency’s director of food additive safety.”We haven’t changed our view that right now, there is not a safety concern, not a public health concern,” she said. “But what we need to do is understand how benzene forms and to ensure the industry is doing everything to avoid those circumstances.”

The admission contradicted statements last week, when officials said FDA found insignificant levels of benzene.

In fact, a different study found benzene at four times the tap water limit, on average, in 19 of 24 samples of diet soda.

The formation of benzene in soft drinks is from the reaction of ascorbic acid (aka Vitamin C) and benzoate salts, notably sodium benzoate which is used as a preservative. As the FDA letter states:

We learned that elevated temperature and light can stimulate benzene formation in the presence of benzoate salts and vitamin C, while sugar and EDTA salts inhibit benzene formation.

Is this a pressing concern? First of all, exposure modeling done by the EPA indicates that 93% of all benzene exposure is through inhalation (cigarette smoke, indoor offgassing, that wonderful refueling smell!), with 7% exposure through oral ingestion. So, potentially elevated levels in this 7% fraction are not likely to greatly increase exposure. In addition, the 5 parts per billion level for drinking water is set based on an assumed daily consumption of 2 liters per day (Source – USEPA), a safety factor up from the actual estimated 0.9-1.2 L per day measured consumption. Assuming the average amount of benzene in soda (mainly diet, mind you) is 4 times that of drinking water, a 500 ml dose of diet soda per day is required to equal the dose from drinking water, which mind you, only counts for 7% of the total bezene exposure. So in a sense, a person drinking 2 servings of diet soda per day would exceed the exposure from drinking water at the federally regulated level, and knock the socks off the California standard of 0.13 ppb in water. This will increase his/her known oral exposure. The total exposure to benzene of that individual, however, would not go up significantly because the overwhelming majority of the exposure still occurs through the nose, not through the mouth.

The issue here, and benzene is just the symptom, is that consumers know much more about their drinking water than they do about their manufactured food products, and that is not good for the consumer or for the industry because in the absence of knowledge and full disclosure, both parties are vulnerable. Which is why attempts to limit consumer knowledge hurt everyone.

Conclusion Please don’t stop drinking soda because of this, I am sure you can find plenty of other reasons to limit your soda consumption… Drink lots of filtered tap water, it’s the best!! And, I can assure you that most tap water is tested thoroughly, it’s zero calories and cheap!

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    Vote Strategically for the Environment

    via Vote For Environment / Voter Pour l’Environnement.

    This site wants you to vote strategically to avoid splitting the anti-conservative vote on the assumption that all things being equal, the conservatives are much worse for the environment than any of the other parties. This is not really how you want an election to be decided, but a party that represents the minority of Canadians should not get a parliamentary majority simply because of a flawed voting system.

    I would heartily endorse a preferential ballot system for us. How does this work?

    Instant-runoff voting (IRV) is a voting system used for single-winner elections in which voters have one vote and rank candidates in order of preference. If no candidate receives a majority of first preference rankings, the candidate with the fewest number of votes is eliminated and that candidate’s votes redistributed to the voters’ next preferences among the remaining candidates. This process is repeated until one candidate has a majority of votes among candidates not eliminated. The term “instant runoff” is used because IRV is said to simulate a series of run-off elections tallied in rounds, as in an exhaustive ballot election.

    Under this system, if you like the Green Party the best because of their environmental policies, but know they cannot win, you can still vote for them. Just have the liberals/NDP as the second choice. It is overwhelmingly likely that if you like the Green Party policies, you like the policies of the conservatives more than the policies of the liberals or the NDP. With our current system, that’s exactly what your vote will say. Your vote for a Green Party candidate in this election is essentially a vote for the Conservatives.

    In the absence of the preferential ballot, or instant runoff voting, using web 2.0 methods to vote strategically is the next best thing, and a great idea!

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    PFOA emissions from Non stick cookware and Popcorn Bags

    Important research coming out of NY. See here for previous PFOA posts. Perfluorinated compounds are used in the manufacture of Teflon, and are bioaccumulative. The theory is that the salts left over in the manufacture (residuals) are offgassing during use, and exposing consumers to bioaccumulative compounds.

    Cast Iron, anyone!!

    Quantitation of Gas-Phase Perfluoroalkyl Surfactants and Fluorotelomer Alcohols Released from Nonstick Cookware and Microwave Popcorn Bags

    Fluoropolymer dispersions are used for coating certain cookware products and food-contact packaging to impart oil and water repellency. Since salts of perfluorooctanoic acid (PFOA) are used as a processing aid in the manufacture of many fluoropolymers, it is necessary to determine if these compounds are still present as residuals after the process used to coat nonstick cookware or packaging, and could be released during typical cooking conditions. In this study, we identified and measured perfluoroalkyl carboxylates (PFCAs), particularly PFOA, and fluorotelomer alcohols (FTOHs; 6:2 FTOH and 8:2 FTOH), released from nonstick cookware into the gas phase under normal cooking temperatures (179 to 233 C surface temperature). PFOA was released into the gas phase at 7-337 ng (11-503 pg/cm2) per pan from four brands of nonstick frying pans. 6:2 FTOH and 8:2 FTOH were found in the gas phase of four brands of frying pans, and the sources of FTOHs released from nonstick cookware are under investigation. We observed a significant decrease in gas-phase PFOA following repeated use of one brand of pan, whereas the other brand did not show a significant reduction in PFOA release following multiple uses. PFOA was found at >5 ng during the fourth use of both brands of pans. FTOHs were not found after the second use of either brand of pans. PFOA was found at 5-34 ng in the vapors produced from a prepacked microwave popcorn bag. PFOA was not found in the vapors produced from plain white corn kernels popped in a polypropylene container. 6:2 FTOH and 8:2 FTOH were measured in the vapors produced from one brand of prepacked microwave popcorn at 223 ± 37 ng and 258 ± 36 ng per bag, respectively, but not measured at >20 ng (LOQ) in the other two brands. On the packaging surface of one brand of microwave popcorn several PFCAs, including C5-C12, 6:2 FTOH, and 8:2 FTOH, were found at concentrations in the order of 0.5-6.0 ng/cm2. This study suggests that residual PFOA is not completely removed during the fabrication process of the nonstick coating for cookware. They remain as residuals on the surface and may be off-gassed when heated at normal cooking temperatures.

    More later.

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    Opinion Polls and Yes Prime Minister

    This story from the grist about a push poll arranged by Rasmussen showing 67% support for the reinstatement of offshore oil drilling in the United States reminded me of this most delightful exchange from Yes Prime Minister, still one of my all time favourite television shows and one that taught me almost everything I needed to know about parliamentary politics at a tender age. The show is about British politics through the eyes of an earnest but bumbling politician, his very experienced bureaucratic handler and his secretary with divided loyalties. The show is incredibly insightful and funny at the same time. But, before I get to my favourite part, some background…

    It’s that time of the year when the republicans want to enrich their oil buddies by opening up oil drilling offshore of the U.S. This year, the high price of gas provides a convenient excuse and rallying point. After all, who wouldn’t want to pay less for gas. Of course, a U.S government study done by the Energy Information Administration in 2007 indicates that at best, you would see a 3% increase in production by 2030, and we all know how much that would affect gasoline prices this summer. Yet, here’s the first question from the “poll”

    In order to reduce the price of gas, should drilling be allowed in offshore oil wells off the coasts of California, Florida, and other states

    No really, what are you supposed to say? Can such reputable firms lie to you like that? Anyway, Joseph Romm from the original gristmill post breaks it down completely so I don’t have to. but after reading his post, come back and read the following exchange from Yes Prime Minister, and do listen to the actual audio clip from the show.

    Yes Prime Minister – Season 1Episode 2 (warning: Strangely formatted website)

    Sir Humphrey: “You know what happens: nice young lady comes up to you. Obviously you want to create a good impression, you don’t want to look a fool, do you? So she starts asking you some questions: Mr. Woolley, are you worried about the number of young people without jobs?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Are you worried about the rise in crime among teenagers?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think there is a lack of discipline in our Comprehensive schools?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think young people welcome some authority and leadership in their lives?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think they respond to a challenge?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Would you be in favour of reintroducing National Service?”

    Bernard Woolley: “Oh…well, I suppose I might be.”

    Sir Humphrey: “Yes or no?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Of course you would, Bernard. After all you told you can’t say no to that. So they don’t mention the first five questions and they publish the last one.”

    Bernard Woolley: “Is that really what they do?”

    Sir Humphrey: “Well, not the reputable ones no, but there aren’t many of those. So alternatively the young lady can get the opposite result.”

    Bernard Woolley: “How?”

    Sir Humphrey: “Mr. Woolley, are you worried about the danger of war?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Are you worried about the growth of armaments?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think there is a danger in giving young people guns and teaching them how to kill?”

    Bernard Woolley: “Yes”Sir Humphrey: “Do you think it is wrong to force people to take up arms against their will?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Would you oppose the reintroduction of National Service?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “There you are, you see Bernard. The perfect balanced sample.”

    That is what I think about opinion polls!

  • Pesticide Screening Using a CD Player and CDs.

    Who said CDs were dead, this is, hands down, the coolest paper on screening techniques I have seen in a while. I haven’t seen the rest of the paper, not Open Access, of course, but the abstract does make it sound cool.

    Microimmunoanalysis on Standard Compact Discs To Determine Low Abundant Compounds

    “High-density competitive indirect microimmunoassays were performed in both sides of compact discs by direct absorption of immunoreagents on polycarbonate surface, using gold- or enzyme-labeled immunoglobulins as tracers for displaying the immunoreaction. The operational principle is based on the use of a low-reflectivity compact disc as analytical platform that allows the reflection/transmission (30/70%) of the CD reader laser beam ( 780 nm). The reflected light is used to scan the disc track keeping it in movement. The transmitted light is detected by a planar photodiode integrated on the CD drive. The variation of the optical transmission of the light caused by the immunoreaction products is related to the sample concentration. As a proof of concept, low abundant compounds, commonly used as pesticides, were detected in a 60-min total assay time, with a limit of detection ranging from 0.02 to 0.62 ug/L for 2,4,5-TP, chlorpyriphos, and metolachlor. The obtained results show the enormous prospective of compact discs in combination with CD players for multiresidue and drug discovery applications.”

    Why are techniques like these important in the world of environmental analysis? Because they change the paradigm from laboratory based techniques to field based analysis. You don’t have to take a bunch of samples, spend a lot of time and money shipping them to a lab and waiting for the results. You can pop your samples into a CD player and one hour later (less than a 74 minute listening time on a CD!), you’ll have results.

    Awesome stuff, I’d love to see it in action, or even try to replicate the work. It looks like you have to make some modifications to the player to make it work, but hey, there are millions of CD players that are going to be obsoleted in the next few years.

  • EPA not conducting Environmental Justice Reviews

    The Environmental Justice movement was started to deal with disparities in the treatment of environmental issues that could be traced back to race/class. It’s disheartening to know that the EPA, which has a mandate to specifically deal with EJ issues has dropped the ball. The next time a landfill/hog factory gets sited near an economically depressed neighborhood, you know why.

    Environmental agency inspector criticizes agency’s lack of fairness on reviews – iht,america,US Environmental Justice – Americas – International Herald Tribune

    The Environmental Protection Agency is not conducting required reviews to ensure that low-income and minority neighborhoods get the same environmental protection as other communities. The report by the EPA’s inspector general, made public Tuesday, said senior EPA officials have not required regional offices and department heads to conduct environmental justice reviews despite a requirement for such reviews dating from 1994. A survey by the IG’s office found 60 percent of the regional offices and program departments that responded had not conducted the reviews, and 87 percent said they had not been asked to do them, according to the report. Such reviews were required by an executive order that former President Bill Clinton issued in 1994. It was reaffirmed by EPA administrators in 2001 and again last year, said the report by acting Inspector General Bill Roderick. Until adequate reviews are conducted, “The agency cannot determine whether its programs cause disproportionately high and adverse human health or environmental effects on minority and low-income populations,” the report said.

  • BC Carbon Tax regressive?

    British Columbians with low incomes will benefit from the carbon tax in its first year, but will pay more by the scheme’s third year, a new study concludes.

    The impact of the tax and its offsetting income tax cuts will become increasingly unequal unless the provincial government increases payments to low-income earners, the study says.

    The study, by Marc Lee, senior economist with the Canadian Centre for Policy Alternatives, and Toby Sanger, senior economist with the Canadian Union of Public Employees, takes a detailed look at the fairness of the controversial tax.

    via Carbon Tax Whacks the Poor, Later :: News :: thetyee.ca

    The report makes some good points. Revenue neutrality (the offsetting of carbon taxes with income/corporate tax cuts) has nothing to do with reducing carbon emissions. If I were to redesign this tax, I would do as the report says, increase rebates to lower income people, reduce corporate tax cuts so that the resulting revenue can be used to fund more transit infrastructure, energy efficiency infrastructure and the building of a low carbon economy.

    A carbon tax in itself is not sufficient to reduce emissions. It does its part, but building an energy efficient, low carbon infrastructure will do a lot more and the money’s there, just use it.

    You can read the whole report here.