Pesticides

farmerA friend pointed me in the direction of this letter by EPA union leaders about the upcoming re-registration of some very commonly used organophosphate and carbamate pesticides. This ens-newswire article provides an excellent summary.

In the absence of “a robust body of data” the union leaders remind Johnson that the Food Quality Protection Act requires the EPA to use “an additional 10-fold safety factor in its risk assessments when setting pesticide tolerances.

This is the key point, and the reason that Pesticide industry and the EPA came up with the infamous “CHEERS” study (talk about Kafkaesque naming!) to study children’s exposure knowing fully well that they would not be able to accurately assess health effects on children with an observational study. The hope was that using a short term “study” that assessed acute toxicity, they would be able to “prove” no significant harm to children and get rid of the safety factor. A factor of 10 is big, and the pesticide manufacturers hate it because the tolerances become low enough that people will be over-exposed.

Isn’t that the whole point of a safety factor? We are still figuring out what happens at low levels of exposure to certain pesticides. This is truly an Environmental Justice issue. It is not the children of EPA administrators eating non-organic fruits and veggies that are going to be exposed. The gains from eating organic food vs. non-organic are dwarfed by the incidental exposure of the families of farmworkers and other people applying pesticides. Yes, you guessed it, they do not tend to be particularly rich or influential, but they are most in need of protection from government to ensure that their children do not get exposed to levels that may be harmful. This is not about shopping at Whole Foods, which is where most of elite America hears about pesticides, this is about the people being exposed to much higher doses. The safety factor is a must to keep them safe.

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    On Google map, everythings back to normal after Katrina | Chron.com – Houston Chronicle

    TBTB (Too busy to blog), but this struck me as very weird.

    On Google map, everythings back to normal after Katrina | Chron.com – Houston Chronicle

    Google’s popular map portal has replaced post-Hurricane Katrina satellite imagery with pictures taken before the storm, leaving locals feeling like they’re in a time loop and even fueling suspicions of a conspiracy.

    Scroll across the city and the Mississippi Gulf Coast, and everything is back to normal: Marinas are filled with boats, bridges are intact and parks are filled with healthy trees.

    “Come on,” said an incredulous Ruston Henry, president of the economic development association in New Orleans’ devastated Lower 9th Ward. “Just put in big bold this: ‘Google, don’t pull the wool over the world’s eyes. Let the truth shine.’ “

    I am sure there is the usual, non-conspiracy involving explanation to all of this, and I don’t know enough about NO geography to even verify this fact, but an explanation would be nice!

    Update:

    Turns out there was a major upgrade of the imagery on the 29th of March. Still does not explain the above…

  • Volcanos and Climate Geoengineering

    The first thing that occurred to me when I heard about the Sarychev eruption was whether it was going to be large enough to inject significant quantities of sulphate aerosol into the stratosphere. Apparently, it is.

    Sarychev Eruption Generates Large Cloud of Sulfur Dioxide

    When sulfur dioxide reacts with water vapor, it creates sulfate ions (the precursors to sulfuric acid), which are very reflective. Powerful volcanic eruptions can inject sulfate aerosols into the stratosphere, beyond the reach of cleansing rainfall. At these altitudes, the sulfates can linger for months or years, cooling the climate by reflecting incoming sunlight. (The effect is stronger when the eruptions occur at tropical latitudes.) Carn says the persistence of such high concentrations of sulfur dioxide in the OMI data throughout the week indicates that the plume from Sarychev Peak reached high altitudes. Data from other satellites (such as CALIPSO) suggest that the volcanic plume reached altitudes of 10–15 kilometers, and perhaps as high as 21 kilometers.

    In 1991, the eruption of Mount Pinatubo in the Philippines injected enough sulphate into the atmosphere to cause a 0.5° C drop in global temperature. This was caused by about 20 million tonnes of SO2. We are nowhere close to these kind of emission levels. After all, Pinatubo was one of the two biggest volcanic events of the century.

    Injecting sulphate particles into the stratosphere has been proposed for a while now, I first wrote about it in 2006 when a prominent atmospheric chemist, Paul Crutzen wrote an article proposing this. The science behind this proposal is basic, sulphate aerosols of the size that would be formed from the oxidation of SO2 are the right size to scatter and reflect solar radiation back into space (my Masters thesis did a first order estimate of this effect from Indian emissions!). If injected directly into the stratosphere, they can stay there for a long time and will not deposit to the the Earth’s surface as acid rain. The issue is managing all the crazy regional variations in climate that would result, and the attendant complications in assigning blame, etc. It would also not help the oceans, which would acidify to hell with all the CO2.

    Anyway, so much for that, the volcano is causing all kinds of havoc with Pacific travel and making for all kinds of cool pictures, which are about the most interesting thing happening at this point in time. We shall see how the sulphate situation plays out in the days to come when the dust settles.

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    Small California Study Finds Correlational Link Between Organochlorine Pesticides and Autism

    That would have been my headline! It was a study of 29 women, and the results show a six-fold increase in the incidence of autism in children whose mothers were close to fields being sprayed with organochlorine pesticides. A factor of 6 is a big number, which is why they found statistical significance at such a low sample size.

    Most organochlorine pesticides (the most famous being DDT) are already banned in the first world. The ones suspected here, endosulfan and dicofol are banned in quite a few countries including Belize, Singapore. Cambodia and Germany. The Stockholm convention (international treaty to identify and restrict the use of persistent organic pollutants) has identified endosulfan as a possible addition to its list of POPs.

    Of course, the US has not even ratified the Stockholm convention thanks to the pesticide lobbies. So, nothing the Stockholm convention decides about endosulfan will  carry any legal weight. In this country, pesticides and most other chemicals in current use are “innocent until proven guilty”, meaning harm must be conclusively proven in a manner that will withstand court challenge. With industry sponsored research and lobbying, such a burden of proof is often insurmountable and therefore, hazardous pollutants are used in the US well beyond their sell-by dates.

    Pesticide link to autism suspected – Los Angeles Times

    Women who live near California farm fields sprayed with organochlorine pesticides may be more likely to give birth to children with autism, according to a study by state health officials to be published today. The rate of autism among the children of 29 women who lived near the fields was extremely high, suggesting that exposure to the insecticides in the womb might have played a role. The study is the first to report a link between pesticides and the neurological disorder, which affects one in every 150 children. But the state scientists cautioned that their finding is highly preliminary because of the small number of women and children involved and lack of evidence from other studies.

    Clearly, the increase in autism incidence has many more factors linked to it than environmental chemical exposure, but this is interesting and good work. This study will doubtless be severely criticized by the pesticide lobby. After all, it’s only a correlation, no mechanism has been proposed, and the sample size is very small. But, as I mentioned before, you don’t normally see six-fold increases in disease incidences with ambient environmental exposure, so there is definitely something going on here.

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    The Pump handle and Diacetyl

    The Pump Handle looks at the response of various government agencies (notionally charged with protecting American people) to increasing information about the danger of diacetyl exposure, certainly to workers in the flavoring industry, and recently, to consumers of microwave popcorn. An excellent post, deserves wider reading!


    Popcorn Lung Coming to Your Kitchen? The FDA Doesn’t Want to Know « The Pump Handle

    The CDC, FDA, OSHA, EPA – federal agencies charged with protecting public health – each received a letter in July alerting them to the possible serious respiratory hazard to consumers who breathe in fumes from their artificially butter-flavored microwave popcorn. The warning should have resulted in some action by these agencies, but instead, they’ve done virtually nothing.

    It appears that the Bush Administration’s efforts to destroy the regulatory system are succeeding; the agencies seem unable to mount a response to information that a well-functioning regulatory system would immediately pursue. The agencies aren’t even trying to connect the dots.

    Read on. I moved to the US in 1997 and I’ve noticed a stark difference in the performance of the government agencies named here. I have no doubt that the agencies will eventually bounce back under the right circumstances, but it is disheartening how far agencies such as the EPA, once regarded as models of well run government (at least to a developing country!) have fallen.

  • Benzene in soft drinks – Flavor of the Month?

    Benzene Levels in Soft Drinks Above Limit – Yahoo! News

    WASHINGTON – Cancer-causing benzene has been found in soft drinks at levels above the limit considered safe for drinking water, the Food and Drug Administration acknowledged Wednesday.
    Even so, the FDA still believes there are no safety concerns about benzene in soft drinks, or sodas, said Laura Tarantino, the agency’s director of food additive safety.”We haven’t changed our view that right now, there is not a safety concern, not a public health concern,” she said. “But what we need to do is understand how benzene forms and to ensure the industry is doing everything to avoid those circumstances.”

    The admission contradicted statements last week, when officials said FDA found insignificant levels of benzene.

    In fact, a different study found benzene at four times the tap water limit, on average, in 19 of 24 samples of diet soda.

    The formation of benzene in soft drinks is from the reaction of ascorbic acid (aka Vitamin C) and benzoate salts, notably sodium benzoate which is used as a preservative. As the FDA letter states:

    We learned that elevated temperature and light can stimulate benzene formation in the presence of benzoate salts and vitamin C, while sugar and EDTA salts inhibit benzene formation.

    Is this a pressing concern? First of all, exposure modeling done by the EPA indicates that 93% of all benzene exposure is through inhalation (cigarette smoke, indoor offgassing, that wonderful refueling smell!), with 7% exposure through oral ingestion. So, potentially elevated levels in this 7% fraction are not likely to greatly increase exposure. In addition, the 5 parts per billion level for drinking water is set based on an assumed daily consumption of 2 liters per day (Source – USEPA), a safety factor up from the actual estimated 0.9-1.2 L per day measured consumption. Assuming the average amount of benzene in soda (mainly diet, mind you) is 4 times that of drinking water, a 500 ml dose of diet soda per day is required to equal the dose from drinking water, which mind you, only counts for 7% of the total bezene exposure. So in a sense, a person drinking 2 servings of diet soda per day would exceed the exposure from drinking water at the federally regulated level, and knock the socks off the California standard of 0.13 ppb in water. This will increase his/her known oral exposure. The total exposure to benzene of that individual, however, would not go up significantly because the overwhelming majority of the exposure still occurs through the nose, not through the mouth.

    The issue here, and benzene is just the symptom, is that consumers know much more about their drinking water than they do about their manufactured food products, and that is not good for the consumer or for the industry because in the absence of knowledge and full disclosure, both parties are vulnerable. Which is why attempts to limit consumer knowledge hurt everyone.

    Conclusion Please don’t stop drinking soda because of this, I am sure you can find plenty of other reasons to limit your soda consumption… Drink lots of filtered tap water, it’s the best!! And, I can assure you that most tap water is tested thoroughly, it’s zero calories and cheap!

  • Canada – No new coal plants?

    For a minute I thought the pain from playing volleyball last night, plus opening my computer up sleepily at 5:45 in the morning before catching an early bus to work had me hallucinating, but yes, the Canadian federal government actually wants to impose a moratorium on the construction of new coal fired power plants unless they include sequestration (which to me means no new power plants).

    The federal government is planning sweeping new climate-change regulations for Canada's electricity sector that will phase out traditional coal-fired power

    Any new coal plants will have to include highly expensive – and unproven – technology to capture greenhouse gas emissions and inject it underground for permanent storage, Environment Minister Jim Prentice said in an interview yesterday.

    Ottawa also plans to impose absolute emission caps on utilities' existing coal-fired power plants and establish a market-based system to allow them to buy credits to meet those targets, Mr. Prentice said.

    via reportonbusiness.com: Ottawa takes aim at coal power.

    I have a certain distrust for this government, so details are crucial. The right things are being said:

    1. All new plants will need sequestration
    2. A cap and trade to deal with existing coal fired power plants
    3. Phase out of facilities after “fully amortized life” – Not clear on exactly what that means
    4. 90% Emissions free power sector by 2025

    As the article points out, Canada relies on coal much less than a lot of other countries, only 18% of current emissions are from coal, as opposed to the US, where about 40% is from coal.

    So, time to celebrate? Not exactly. Canada’s latest release of 2007 data indicates horrendous performance.

    Canada 2007 GHG Inventory

    Overall, total increase was 6 Megatonnes from 2004 to 2007. But the increases from the Tar Sands were nearly 16 Mt, meaning most of Canada’s other sectors saw decreases, thanks to a number of mild winters and greater efficiency.

    Clearly, this performance is going to continue until the Tar Sands are included in any CO2 reduction strategies, whatever we do, or don’t do with the coal will have a little bit of impact, but will definitely not help Canada achieve any of its short or long term goals.

    So, one cheer for this announcement. I suspect that the administration needs something to take to meetings, and is hoping that a coal moratorium will distract people from the biggest culprits, the Tar Sands and our insanely high per capita GHG footprint. A “no new coal” moratorium would be a huge deal in the States, and off the charts in China or India as far as reducing emissions go. But Canada, not bad, but definitely not good enough!

    The Tar Sands will only be stopped when the US steps up to the plate and gets its Cap and Trade going.