Nanoparticles the new asbestos?

I am sure everyone has heard about the wonders of nanotechnology, but what about the other side?

ScienceDaily: Tiny Inhaled Particles Take Easy Route From Nose To Brain

In a continuing effort to find out if the tiniest airborne particles pose a health risk, University of Rochester Medical Center scientists showed that when rats breathe in nano-sized materials they follow a rapid and efficient pathway from the nasal cavity to several regions of the brain, according to a study in the August issue of Environmental Health Perspectives

There was a time when asbestos was the wonder material, malleable and fire resistant, capable of being woven into sheets, and being incorporated into buildings for fire retardation. Unfortunately, many cases of asbestosis and mesothelioma later, not so wonderful. Asbestos is a special case because the fibers started out big and would keep breaking down into smaller particles till they reached that magic size range between 0.1 and 1-2 um where they could stay suspended in the air for a long time, and also take advantage of the lungs’ inability to filter particles that size to any great degree of efficiency.

Nanoparticles are an order of magnitude smaller, and hence behave more like gases. They may  also contain choice toxic heavy metals such as manganese which are not usually floating around in the air at these small sizes. So, this study is a little scary, especially for the folks in the manufacturing end of things, these miracle particles seem to be going straight to the brain. Traditional masks and air handling systems are not designed to filter such fine particles, so I am sure they’re floating around in the air waiting to be breathed in.

Update 9:00 AM, 8-3-2006
Well, I swear, I did not see this before I wrote this morning!

The question of the day, however, is are they safe for humans and other living things? Earlier this year, Andrew Seaton, A U.K. scientist who was the lead author of a 2004 report investigating the saftey of nanotechnological materials raised a bit of a ruckus by comparing carbon nanotubes to asbestos fibers. Asbestos once had its day in the sun as an all-purpose wonder material. But then we learned that tiny asbestos fibers, once ingested by the human body, could be extremely deadly. Carbon nanotubes: also easy to ingest, and exquisitely capable of penetrating cell structures. Could they be equally toxic?

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    Opinion Polls and Yes Prime Minister

    This story from the grist about a push poll arranged by Rasmussen showing 67% support for the reinstatement of offshore oil drilling in the United States reminded me of this most delightful exchange from Yes Prime Minister, still one of my all time favourite television shows and one that taught me almost everything I needed to know about parliamentary politics at a tender age. The show is about British politics through the eyes of an earnest but bumbling politician, his very experienced bureaucratic handler and his secretary with divided loyalties. The show is incredibly insightful and funny at the same time. But, before I get to my favourite part, some background…

    It’s that time of the year when the republicans want to enrich their oil buddies by opening up oil drilling offshore of the U.S. This year, the high price of gas provides a convenient excuse and rallying point. After all, who wouldn’t want to pay less for gas. Of course, a U.S government study done by the Energy Information Administration in 2007 indicates that at best, you would see a 3% increase in production by 2030, and we all know how much that would affect gasoline prices this summer. Yet, here’s the first question from the “poll”

    In order to reduce the price of gas, should drilling be allowed in offshore oil wells off the coasts of California, Florida, and other states

    No really, what are you supposed to say? Can such reputable firms lie to you like that? Anyway, Joseph Romm from the original gristmill post breaks it down completely so I don’t have to. but after reading his post, come back and read the following exchange from Yes Prime Minister, and do listen to the actual audio clip from the show.

    Yes Prime Minister – Season 1Episode 2 (warning: Strangely formatted website)

    Sir Humphrey: “You know what happens: nice young lady comes up to you. Obviously you want to create a good impression, you don’t want to look a fool, do you? So she starts asking you some questions: Mr. Woolley, are you worried about the number of young people without jobs?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Are you worried about the rise in crime among teenagers?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think there is a lack of discipline in our Comprehensive schools?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think young people welcome some authority and leadership in their lives?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think they respond to a challenge?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Would you be in favour of reintroducing National Service?”

    Bernard Woolley: “Oh…well, I suppose I might be.”

    Sir Humphrey: “Yes or no?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Of course you would, Bernard. After all you told you can’t say no to that. So they don’t mention the first five questions and they publish the last one.”

    Bernard Woolley: “Is that really what they do?”

    Sir Humphrey: “Well, not the reputable ones no, but there aren’t many of those. So alternatively the young lady can get the opposite result.”

    Bernard Woolley: “How?”

    Sir Humphrey: “Mr. Woolley, are you worried about the danger of war?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Are you worried about the growth of armaments?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Do you think there is a danger in giving young people guns and teaching them how to kill?”

    Bernard Woolley: “Yes”Sir Humphrey: “Do you think it is wrong to force people to take up arms against their will?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “Would you oppose the reintroduction of National Service?”

    Bernard Woolley: “Yes”

    Sir Humphrey: “There you are, you see Bernard. The perfect balanced sample.”

    That is what I think about opinion polls!

  • Dear American Public Media, Coal is not clean!

    Overheard this morning on The Marketplace morning report…

    “The use of scrubbers have made coal fired power plants much cleaner”

    Umm, this only refers to the scrubbing of particulate matter and sulfur dioxide. Unless some marvelous scrubber has been invented and perfected (top secret, the coal fired power plants don’t want you to know about all the good things they do!) that picks up all the CO2 belching out of those smokestacks, no claim can be made that coal is cleaner.

    Dear Marketplace, your own website says the following:

    KAI RYSSDAL: And it’s official. Carbon dioxide is a pollutant. The Supreme Court says so. The Bush Administration had been arguing the Environmental Protection Agency doesn’t have the authority to regulate greenhouse gases

    To argue this from a strictly legalistic standpoint, coal is dirtier now than it has ever been because we finally count CO2 as a pollutant (Yes, I know, Supreme Court only ruled on automobile emissions because that was the case in front of it, but gas is gas!).

    Dear Marketplace, please stop using the words clean and coal in the same sentence unless and until CO2 emissions from coal are scrubbed!

    Update 30Aug07: Apparently (see comments!), NPR does not like the use of the word NPR in the blog title because (and I quote)

    “Marketplace” is not an NPR show. It is produced by American Public Media, a separate company, and has its own news operation”

    True, so it’s not dear NPR anymore, it’s “dear American Public Media”. There, that takes care of that. My point obviously stands, coal is not clean!!

  • BC's Carbon Tax Chugs Along

    Premier Gordon Campbell says he won’t bend to northern concerns about his carbon tax, but avoided saying so yesterday in a keynote speech to a meeting of northern B.C. communities, who have challenged him to revise the tax.

    reportonbusiness.com: ‘We are not changing the carbon tax. No,’ B.C. Premier says

    One of the loudest arguments being made against BC’s pioneering carbon tax proposal is that communities in Northern BC, much colder and much more rural than Vancouver and Victoria, will pay an “unfair” share because they need more carbon to heat their homes and drive their cars/trucks longer distances. The weather and lack of density ensure that they will pay higher carbon taxes, so it is unfair.

    Well, sorry! Victoria and Vancouver have been paying a fair weather premium for years in higher home prices, higher property taxes, higher prices on lots of things because that’s what city dwellers do without complaint. You can buy an average single family home in Prince George for $125,000, which may get you a garage in Vancouver!

    Cities are more efficient, and use far less energy per capita because of the density and transit options. Pricing carbon starts bringing some of these efficiencies to the forefront and that is a good thing.

    BC’s carbon tax is not perfect by any means. But, it is a start and it gets people thinking about consumption. Believe me, carbon’s on a lot of people’s minds here in BC. There’s tons of talk about carbon sinks and sources in the media. The carbon tax has definitely contributed to an increase in conversation about choices and their consequences. The funny thing is that the proposed carbon tax on gasoline has been dwarfed by actual market driven increases in gasoline prices. The important difference is that a carbon tax is a revenue stream that goes to funding carbon free energy sources. So, a tax, however small, is still preferable to the profits going to companies that deal in carbon.

    Hurray for BC and its carbon tax attempts. It is a decent start and one that I hope will be adopted by the rest of Canada and that wee country south of the border!

  • 'Shocking' conditions at Kenya dump

    B26F0EF1-45A5-4229-9FE0-83784AA06DBC.jpg

    As part of blog action day, today’s a day when every blog features a post about the environment. Turns out that this is an environmental blog where most of the posts are about the environment. But nothing like a deadline for a noble cause to make me blog, so here goes…

    What the rich use and throw away, the poor are reduced to scavenging to earn a meager living. Yes, while climate change rightly takes up a lot of attention, more mundane problems including landfills in poor communities, the export of waste from the first world to the third world, and the “shocking” poverty that drives this export of waste all deserve their fair share of attention.

    U.N.: ‘Shocking’ conditions at Kenya dump – World Environment – MSNBC.com

    “Willis Ochieng, 10, scavenges through smoking refuse piled as high as a house at one of Africa’s biggest rubbish mountains, his friends sitting nearby sucking on dirty plastic bottles of noxious yellow glue.

    Located near slums in the east of the Kenyan capital Nairobi, the open dump receives some 2,000 tons of garbage daily. A U.N. study published on Friday says it is seriously harming the health of children and polluting the city.”

    And boy, do the people there suffer. Asthma, anemia, high levels of lead in the blood, chronic cough, and a smorgasbord of other acute and chronic conditions.

    This dump is not alone, of course. Landfills are a feature of every country, and in my current home state of North Caroiina, are located with disproportionate frequency in African American communities. the free market advocate would say that this represents an opportunity for the people in the community to gain some employment and make some money. The truth of the matter, however, is that we do not pay the right price for waste generation. The people who live near, and make a living off the “dump” subsidize our profligate selves.

  • Combating Global Warming with Frankensulfates

    I don’t quite know how to react.

    Chemical & Engineering News: Latest News – Support Voiced For Geo-Engineering Research To Combat Global Warming

    The call to at least consider audacious geo-engineering steps that would fill the stratosphere with globe-cooling aerosols to check global warming got louder last week. In Science, Tom M. L. Wigley of the National Center for Atmospheric Research, in Boulder, Colo., writes that reducing carbon dioxide emissions is the long-term solution to global warming but that nearer term engineering of the atmosphere might provide “additional time to address the economic and technological challenges faced by a mitigation-only approach” (DOI: 10.1126/science.1131728). Last month, Nobelist Paul J. Crutzen of the Max Planck Institute for Chemistry, in Mainz, Germany, made headlines with an essay in the journal Climatic Change calling for more research into the pros and cons of injecting sulfate-based aerosols into the stratosphere as a sunlight-reflecting, cooling foil to global warming (C&EN, Aug. 7, page 19).

    The paper is still not out for public consumption, because “YOUR INSTITUTIONAL SUBSCRIPTION DOES NOT INCLUDE THIS ITEM:” (How an organization that is funded wholly by government (taxpayer) money can publish in journals that make you pay to read their contents is the subject of a different rant). Nevertheless, this modeling effort builds on Crutzen’s earlier essay which I just finished reading.

    Sulfate particles reflect incoming solar radiation, reducing the amount of light incident on earth and lowering the average temperature. This has been known for years, and I am sure every aerosol scientist has thought “Well, if there was some way of putting particles in the atmosphere to reflect more light, this whole global warming thing would just go away”. But the obvious issue with this approach is that sulfates in the troposphere are nasty, they cause acid rain, haze, increased mortality, etc. Crutzen expands on this further.

    The great advantage of placing reflective particles in the stratosphere is their long residence time of about 1–2 years, compared to a week in the troposphere. Thus, much less sulfur, only a few percent, would be required in the stratosphere to achieve similar cooling as the tropospheric sulfate aerosol (e.g., Dickinson, 1996; Schneider, 1996; NAS, 1992; Stern, 2005). This would make it possible to reduce air pollution near the ground, improve ecological conditions and reduce the concomitant climate warming. The main issue with the albedo modification method is whether it is environmentally safe, without significant side effects

    Which I guess is the key question, let alone the practicalities of introducing and maintaining 5.3 Tg (terra grams or million metric tonnes) of sulfur in the stratosphere successfully. This is a 10% increase from the current emissions of 55 Tg/year, so I guess it is not a terribly large number. Crutzen estimates that it will cost 25-30 billion dollars per year to have a loading of 1-2 Tg (to combat the most optimistic global warming scenario), though he cites a personal communication with someone at the National Academy of Sciences in 1992. This number is bogus, how do you know what something will cost if you don’t know how you’re going to do it? Crutzen has some ideas…

    Locally, the stratospheric albedo modification scheme, even when conducted at remote tropical island sites or from ships, would be a messy operation. An alternative may be to release a S-containing gas at the earth’s surface, or better from balloons, in the tropical stratosphere

    In other words, speculation at this point in time. The bottom line is this, the idea is not revolutionary, heck, even I thought of this in the mid 90s when I was doing sulfate aerosol work. The mechanics of how this will be done without causing some unforeseen other major issue is the real question that will take years to answer. Meanwhile, this silly personal virtue called conservation still works, look at this graph (from an NY Times article through the Washington Monthly), if Cali can do it, so can you.

    blog_california_electricity_usage.gif

  • What happens when…

    the national science academies of the 13 most important countries release a landmark strong statement about the state of the world’s energy crisis? According to the grist, nobody listens. Well, here’s to my 10 or so readers (self deprecation is the best deprecation!), the rant!

    Bad news re: good news about bad news | Gristmill: The environmental news blog | Grist

    The bad news is that we are in quite a pickle.

    The good news about the bad news is that the national science academies of the G8 countries, along with those of Mexico, Brazil, South Africa, China, and India, have issued a unanimous and remarkably strong statement about our global energy quandary.

    The bad news about the good news about the bad news is that the press is almost totally silent about it, at least in English-speaking countries.

    Among the crucial statements in this document (PDF):

    • “Our present energy course is not sustainable.”
    • “Responding to this demand while minimizing further climate change will need all the determination and ingenuity we can muster.”
    • “The problem is not yet insoluble but becomes more difficult with each passing day.”
    • “G8 countries bear a special responsibility for the current high level of energy consumption and the associated climate change. Newly industrialized countries will share this responsibility in the future.”

    Let me be as polite as I can stand about this. Where in the @$#! is the press?

    And it goes on in similar vein…

    If you read the pdf, you will note that it has the obvious solutions (obvious to the half alive, that is)

    1. Set standards and promote economic instruments for efficiency, and commit to promoting energy efficiency for buildings, devices, motors, transportation systems and in the energy sector itself.
    2. Promote understanding of climate and energy issues and encourage necessary behavioural changes within
      our societies.
    3. Define and implement measures to reduce global deforestation.
    4. Strengthen economic and technological exchange with developing countries, in order to leapfrog to cleaner and more efficient modern technologies.
    5. Invest strongly in science and technology related to energy efficiency, zero-carbon energy resources and carbon-removing technologies.

    Nothing new here, just a very easy policy framework under which every major action taken by every one of these countries (and others) needs to work. Of course, planning, evaluation, implementation, etc. are difficult, especially on the technology transfer, behavioral change, and deforestation, but evaluate every major decision under this framework. You will see that things like corn ethanol (promotes deforestation, carbon intensive, not energy efficient), coal to liquid technology (carbon intensive, polluting, inhibits behavioral change), suburban sprawl (energy inefficient, inhibits behavioral change, etc.), excessive patent protection and intellectual property rights (inhibits technology transfer), war (well, everything on the list, really!), and I can keep going on, are just plain stupid, irresponsible and will lead the world to ruin.

    just print that framework out (or better still, put it in your PDA) and evaluate every thing you read about energy policy using it. You’ll see why I beat my head against the wall a lot!

    Also, note this simple two sentence evisceration of the “China and India are not doing it, so we won’t” argument…

    G8 countries bear a special responsibility for the current high level of energy consumption and the associated climate change. Newly industrialized countries will share this responsibility in the future

    I would add, of course, that G8 countries bear both current, and historical responsibility, other than that, well said.

One Comment

  1. Prince Charlie (Charlie of the Bombay dabbawallas) was the first celebrity to try to raise on the possible dangers of awareness on nano-particles.

    I was stunned by the reaction of those around me in the university to his attempt. Things like “Bullshit!”,”What makes him an expert?”. It never ceases to amaze me how closed-minded scientists are about science…very dismissive of the lay person. You don’t have to be an expert to express concern about anything. Was Diana an expert on mines? Is Bill Gates an expert on Africa? Is Arundhati Roy an expert on anything at all?

    To celebs who try to use their fame for a good cause… Respek!

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