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Pet Poisonings – A chemistry detective story

Melamine in pet food may not be accidental – USATODAY.com

A nitrogen-rich chemical used to make plastic and sometimes as a fertilizer may have been deliberately added to an ingredient in pet food that has sickened and killed cats and dogs across the country, public and private officials say. A leading theory is that it was added to fake higher protein levels.

Melamine has been found in wheat gluten, rice protein concentrate and, in South Africa, corn gluten, all imported from China, and all meant for use in pet food, the Food and Drug Administration confirmed Thursday.

“It adds to the theory when you see other products that are labeled as protein supplements, in this case rice protein, and in South Africa corn gluten and in the previous case wheat gluten,” said Stephen Sundlof, FDA chief veterinarian. “That melamine was found in all three of those, it would certainly lend credibility to the theory that this was intentional.”

Interesting, apparently, melamine was added to increase the nitrogen content of the food so it would show up as protein in the most common protein test, which only looks for nitrogen. When I am not working, I guess I will look up the test details.

I wonder if this is only the tip of the iceberg? What other techniques do food manufacturers use to fake it? Growing up, food adulteraion was a serious problem in India, and still continues to be an issue in the third world.

More on this story to come, I am sure.

One more thing that needs to be said is that the FDA has been very reactive, as opposed to proactive. This is partly because the FDA does not issue recalls, it first “strongly suggests” that the company involved recall whatver product it is that may be having issues. Only if this issue is not addressed can the FDA start seizure proceedings, which could take months. The FDa regulates and monitors on a company level, not at a product level.

For example, when Japan had one sample of U.S beef test positive for mad cow disease, that was the end of beef imports from the U.S. This is an extreme case because you’re dealing with an infectious disease, but the point is that when you are finding huge levels of pesticide in food from a country, the first thing you need to do is stop everything, troubleshoot, then turn things back on again. Yes, this gets expensive, but so does 1000s of sick pets. The difference is, who pays. In the U.S, it’s always the consumer!

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    I had blogged recently about how one guy gamed an auction of Utah public lands to prevent the sale of sensitive land to oil and gas companies. It looks like he may be off the hook, at least temporarily.

    A federal judge on Saturday blocked oil and natural gas exploration on tens of thousands of acres of federal land in Utah, saying in an 11th-hour decision that the Interior Department had not done sufficient environmental analysis, particularly of how air quality might be degraded.The decision by the judge, Ricardo M. Urbina of Federal District Court in Washington, granted a temporary restraining order sought by seven environmental groups to prevent oil and gas companies from taking possession of leases they had purchased Dec. 19.

    11th-Hour Ruling Blocks Utah Oil and Gas Leases – NYTimes.com

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    Factory Farm Maps

    Want to know where the factory farms are? Want to see a nice graphical representation of the number of hogs, or cows, or chickens that live next to you in factory conditions? Well, look no further than Factory Farm Map.

    You will find, for instance, that Iowa is the hog king at 13 million hogs, followed closely by North Carolina at 9.8 million. However, Iowa has them spread out through the state while North Carolina has them in one part of the state (Down east), exacerbating the concentration of the pollution, and the differential impacts of the pollution with geographical location. There are 2.19 million hogs in Duplin County alone, that is 40+ hogs to every human that lives there, or 25000+ hogs per square mile, nice…

    Anyway, words don’t do the site justice, just go and play with it.

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    Coffee Roasting and Popcorn Lung

    Cross-posted from Interrobang

    Who among us coffee drinkers don’t love the smell of freshly roasted coffee? I am sure some of us imagine how much fun it would be to smell freshly roasting coffee more often. I don’t, because smell for me is an instant jolt of pleasure/pain followed by a rather rapid decline into the background.

    Caution, though. New measurements from the US Centres for Disease Control warn of high exposure to some pretty nasty chemicals that can cause your lungs to be destroyed irreversibly, the unfortunately named “popcorn lung” or bronchitis obliterans:

    Investigators with the National Institute of Occupational Safety and Health, a research arm of the CDC, spent several days at Madison-based Just Coffee in July. Investigators tested personal air space and took air samples to measure the concentration of the chemicals diacetyl and 2,3-pentanedione… NIOSH researchers found levels in three breathing-zone samples that exceeded the safety levels recommended by the CDC.

    Coffee Roasting Plants and Exposure

    The test results show a marginal exceedance in this case, but noted that ventilation is a big factor and these tests were done under well ventilated conditions on a warm and dry day when doors were open. So, exposure can be higher in other circumstances.

    Worker exposures are to higher levels, and are more sustained, so they deserve the most attention.

    So, local coffee roasters, it may make sense to confirm that your roasting environments are not exposing your workers to harmful, lung obliterating chemicals. Remember, organic, shade grown, fair pay, artisanal roasting aside, chemical exposures to workers don’t change. And, everything that smells good isn’t good for you.

    One of my frequent points of emphasis (rants, some might say) is on the relative risk vs. media attention to exposures of people to ambient, day to day concentrations of potential harmful chemicals vs. those faced by workers everywhere. The last time diacetyl and bronchitis obliterans were in the news, it was around the use of diacetyl to produce that buttery smell so beloved in microwave bag popcorn (I don’t like it myself, olive oil all the way!). Despite reports of many workers facing severe lung issues, it took the detection of the disease of one person eating multiple bags of microwave popcorn over many years to actually move government regulators into action on diacetyl. People who work in factories, in the fields, and make things are exposed to thousands of times higher concentrations of harmful chemicals for longer periods of time, but their concerns are often de-emphasized.

    This doesn’t mean ambient exposures in the general population are to be ignored, but worker exposures are to higher levels, and more sustained, so they deserve the most attention.

    16-May-2016 Update

    This US Centers for Disease Control page is a good collection of information and further readings. They recommend facility tests to measure diacetyl and its cousin 2,3-pentanedione, and better ventilation, worker safeguards and personal protective equipment as necessary. They also note that at least five workers in large scale coffee processing plants have been diagnosed with bronchitis obliterans.

    Coffee image By Ailura – Own work, CC BY-SA 3.0

  • Pot Farms Damaging National Parks

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    To avoid the obvious “Pot Legalization” questions and flip it, consider a world where cigarettes have been banned/regulated to the extent that black market growing became viable, would this happen with tobacco? Obviously, the nature of the growing (Tobacco – plains, easy plant to spot, Cannabis – Hill sides, easy to hide), make it an operation question in addition to an economics question. But as the above report states, the operation was obviously not hard to spot, nor was it low impact.

    Something to consider as actions widely prevalent in populations are made illegal, how well does prohibition ever work?

  • GE Plumbs the Depths

    The very excellent htww blog by Andrew Leonard on Salon brought this “clean coal” video to my attention. It is a year old, but new to us!

    Do watch. In a one minute commercial, GE manages to greenwash on clean coal, be incredibly sexist, and, in an act that screams a giant F@#$ You to all involved, use as a soundtrack, a song about the misery of coal mining and the hardship faced by miners. I thought it was a parody, it had to be, apparently, NOT!

    Sixteen Tons

    Some people say a man is made outta mud
    A poor man’s made outta muscle and blood
    Muscle and blood and skin and bones
    A mind that’s a-weak and a back that’s strong

    You load sixteen tons, what do you get
    Another day older and deeper in debt
    Saint Peter don’t you call me ’cause I can’t go
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    I was born one mornin’ when the sun didn’t shine
    I picked up my shovel and I walked to the mine
    I loaded sixteen tons of number nine coal
    And the straw boss said “Well, a-bless my soul”

    You load sixteen tons, what do you get
    Another day older and deeper in debt
    Saint Peter don’t you call me ’cause I can’t go
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    I was born one mornin’, it was drizzlin’ rain
    Fightin’ and trouble are my middle name
    I was raised in the canebrake by an ol’ mama lion
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    You load sixteen tons, what do you get
    Another day older and deeper in debt
    Saint Peter don’t you call me ’cause I can’t go
    I owe my soul to the company store

    If you see me comin’, better step aside
    A lotta men didn’t, a lotta men died
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    Then the left one will

    You load sixteen tons, what do you get
    Another day older and deeper in debt
    Saint Peter don’t you call me ’cause I can’t go
    I owe my soul to the company store

    Shame on them.

  • Carrboro Screening of "After the Peak"

    I happened to watch an interesting short film called After the Peak about peak oil, the concept (not that revolutionary unless you ask Messrs  Exxon-Mobil, Shell and Dick Cheney!) that oil production will start declining after a certain peak production event. The docudrama made by local film maker James McQuaid was part of a public meeting on the local (Orange County, NC) responses to the coming energy crisis. Interesting conceptually, it was shown as a 30 minute local newscast, with the usual cast of characters, the too handsome eye candy anchor and his female sidekick, the young and breathless “street reporter”, the gray haired expert, and the uber-energetic sports guy! The newscast is set a year into the future when the price of gas is $10/gallon. The documentary of interviews with various community members about the effects of the price of gas on their business/life. In the 30 minutes, he touched upon food, school buses, sports, NASCAR, the poor, commutes, etc. It was an interesting effort, if a little over the top! The fake interviews with the racing track owner who’s closing his track down, the UNC athletic director who has to cancel all his long distance events, the manager of the local food store who threatens food scarcity.

    But is $10 a gallon really a big deal?

    gas-prices.png

    This simple chart shows income adjusted dollar per gallon gas prices (gas prices from 2006, income from 2004, but it should not change too much.)

    Let’s avoid the low income outliers and just compare the U.S and Germany. In April 2006, the U.S was paying $2.95 a gallon and Germany, $8.06 per gallon (ref). If you further adjust that with the per capita income of the two countries, $41,300 for the U.S versus $30,500 for Germany (ref), you will find that the price of gas in Germany is well above $10 a gallon already, they seem to be doing just fine! Maybe they just drive less. The US uses 381 million gallons of gas per day (that’s about 1.2 gallons per day per person). I agree that this comparison is a little flawed because the bulk of the German price is due to taxes, which go back to the government and are presumably used for various good deeds. Also, if the price of gas went up due to shortages, the price differential between Germany and the US would presumably stay constant (unless the Germans lowered taxes). My point is that many countries cope with high gas prices quite well, they just don’t make the same choices the Americans make, 1 acre lots, large SUVs, super long commutes, etc. There are a lot of efficiencies to be had here. The graph below shows the income adjusted gasoline price for a few countries (easy data was available!)

    My take: we need to swiftly move away from gasoline by a) Disincentivizing the use of gasoline in transportation b) Incentivizing the use of electricity for transportation. Electricity can be produced more efficiently, and pollution at the source can be controlled more effectively. A combination of a drastic increase in solar and wind power, coupled with aggressive development in battery technology should more than solve our problem without much recourse to biofuels (that great boondongle).

One Comment

  1. meanwhile, we cat owners get paranoid about every hairball and grass related puking our cat exhibits 🙁

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