Black Lung – Miners pay so you can get more coal

Check out this story from the January 26, 2006 LA Times.

In a rare move to phase out a widely used industrial compound, the Environmental Protection Agency announced Wednesday that it was asking all U.S. companies to virtually eliminate public exposure to a toxic chemical used to make Teflon cookware and thousands of other products.

EPA’s system of regulating chemicals leads to some really perverse incentives. The burden of proof shifts to the EPA to prove beyond reasonable doubt that a chemical has definite harmful effects on humans at ambient exposure levels. So the preferred route has been for the EPA to “suggest” to the companies to participate in a voluntary phaseout.

No one knows how the chemical is getting into people’s bloodstreams and in the bodies of polar bears and other animals. Although it is used in production of cookware, it is not found in the cookware, clothing and other fluoropolymers after manufacture.

Well, not quite. This from a paper published in the Environmental Science and Technology on January the 25th.

Polyfluorinated telomer alcohols and sulfonamides are classes of compounds recently identified as precursor molecules to the perfluorinated acids detected in the environment. Despite the detection and quantification of these volatile compounds in the atmosphere, their sources remain unknown. Both classes of compounds are used in the synthesis of various fluorosurfactants and incorporated in polymeric materials used extensively in the carpet, textile, and paper industries. This study has identified the presence of residual unbound fluoro telomer alcohols (FTOHs) in varying chain lengths (C6-C14) in several commercially available and industrially applied polymeric and surfactant materials…

This study suggests that elimination or reduction of these residual alcohols from all marketed fluorinated polymers and fluorosurfactants is key in reducing the prevalence of perfluorinated acids formed in the environment.

Well, that explains it a little better, this article from ES&T provides a nice executive summary like context.

An emerging theory that explains how PFOA (perfluorooctanoic acid) and other PFCAs (perfluorocarboxylic acids) have contaminated the Arctic has received a boost from a new modeling study published in this issue of ES&T (pp 924–930). The theory contends that Arctic contamination is due to atmospheric transport and breakdown of fluorotelomer alcohols, chemicals that are used in products that include stain protectors, microwave-popcorn bags, fast-food wrappers, polishes, and paints.

Well, it sure looks like we need to focus much more on the PFOA precursors rather than on the PFOA itself. Dupont and 3M are not going to be happy about that!

Where for the n’th time, you get to use “EPA”, and “scales back rules” in one sentence.

E.P.A. Scaled Back Rules on Wetlands – New York Times

After a concerted lobbying effort by property developers, mine owners and farm groups, the Bush administration scaled back proposed guidelines for enforcing a key Supreme Court ruling governing protected wetlands and streams. The administration last fall prepared broad new rules for interpreting the decision, handed down by a divided Supreme Court in June 2006, that could have brought thousands of small streams and wetlands under the protection of the Clean Water Act of 1972. The draft guidelines, for example, would allow the government to protect marsh lands and temporary ponds that form during heavy rains if they could potentially affect water quality in a nearby navigable waterway. But just before the new guidelines were to be issued last September, they were pulled back in the face of objections from lobbyists and lawyers for groups concerned that the rules could lead to federal protection of isolated and insignificant swamps, potholes and ditches.

This is the consequence of a tortured Supreme Court ruling from June of last year where Justice Kennedy could not make up his mind on what was a wetland and what was not, so he helped hand down a very confusing verdict open to all kinds of interpretation. At that time, here’s what I said…

This will make things confusing for a while, and you all know who confusion favors!

Well, I told ya!

Turns out that the fugitive emission of nasty sulfur gases in New York that had Fox News suspecting terrorism for a while may have come from more mundane sources.

Sniffing Out the Truth – New York Times

But we haven’t, and we think we can support one of the theories of the odor’s source that has been suggested. Based on our familiarity with the local aquatic environment and regional meteorology, we believe that the odor was caused by gases released from saltwater marshes in the metropolitan area. Let us explain. The intertidal sediments in this region are home to micro-organisms that produce sulfur compounds. When these sediments interact with saltwater that contains low levels of oxygen, gases are released. These gases include hydrogen sulfide and a variety of thiols (like the gas additives thiophane and mercaptan) — all of which have an odor similar to rotten eggs.

First, there was a low tide in the coastal marshes from roughly 4 a.m. to 6 a.m. Second, we experienced winds from the south and an atmospheric inversion, which created something like a low-lying bubble of air.

The result of the two factors? The low tide exposed the marsh sediments and hastened the release of sulfur gases into the atmosphere. The inversion trapped the odor close to the groundand the southerly winds then carried it to Lower Manhattan, where it remained until atmospheric conditions changed.

Damn, this is CSI NY (Atmospheric Chemistry and Modeling Division), good stuff!

Our explanation highlights the consequences of excessive nutrient loading and the resulting low oxygen levels in local coastal waters. (By nutrient loading, we mean exposing water to sewage, fertilizer, chemicals or other pollutants.) Of course, these consequences go beyond odor — they kill marsh vegetation, degrade the wider marine habitat and make it unsafe to swim or fish.

Indeed, so the cause, while natural is not really natural, it is from untreated sewage. New Yorkers, stop blaming New Jersey! Look at yourself!