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You breathe in toxic chemicals too.

Behind a frigging pay wall, as usual! Kelly et al. argue in Science that hydrophobicity, the tendency to favor oil over water (to break it down to the simplest explanation) is not the only factor that explains biomagnification. The underlying theory used to be that compounds that can dissolve in water would swiftly degrade (either chemically or biologically) and not be of any concern to humans. Compounds like dioxins, PCB’s, DDT, etc. accumulated in fat tissue of aquatic animals and these were the compounds that would biomagnify through ingestion (eating!). Kelly et al. uncover another pathway that probably made every scientist go “D’uh”! – Apparently, chemicals animals breathe in can also bioaccumulate if they are not cleared efficiently by the lungs. So, air breathing cows, chickens and pigs can also cause significant bioaccumulation of certain compounds. Which ones? I guess you’ll have to pay to find out more, but this Scientific American article adds some context. Turns out, it is about 10000 chemicals, not all of them known to be harmful, but because they were never suspect, their metabolism is unknown.

Well, if anything, it will keep the biomonitoring folks busy for a while!

Chemical Consequences — 317 (5835): 165g — Science

Global regulators of commercial chemicals apply a scientific paradigm that relates the biomagnification potential of the chemical in food webs to the chemical’s hydrophobicity. However, Kelly et al. (p. 236; see the news story by Kaiser) show that current methods fail to recognize the food web biomagnification potential of certain chemicals. Certain chemicals do not biomagnify in most aquatic food chains, but biomagnify to a high degree in air-breathing animals, including humans, because of low respiratory elimination. Thus, additional criteria for evaluating biomagnification and toxicity in chemicals that biomagnify are required.

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    Meanwhile, in the other India

    While India prepares to spend many billions of dollars on fighter jets, it cannot provide clean water for its citizens.

    Cholera-diarrhoea toll mounts to 164 in Orissa-India-The Times of India

    Cholera and diarrhoea, having assumed epidemic proportions in three tribal dominated Orissa districts, have so far claimed 164 lives as officials confirmed five more deaths in worst-hit Koraput on Thursday.

    The death toll, which had mounted to 159 on Wednesday, further rose to 164 with confirmation of five casualties in Dasmantpur block of Koraput district, Chief District Medical Officer (CDMO) R K Agarwal said.

    While the toll in Koraput district went up to 73, the situation remained by and large unchanged in Rayagada with 64 casualties as the killer diseases claimed as many as 27 lives in Kalahandi, official sources said.

    The water-borne diseases had assumed epidemic form in nine blocks of these three backward districts located adjacent to each other though separated by hills and the waterspread of the vast Indravati reservoir.

    Despite state government’s claim to have effectively controlled the spread of the diseases, residents of the affected areas alleged that the administration had failed to provide adequate medical facilities to the patients.

    This is disgusting and very symptomatic of the urban-rural divide that exists in India. Unless the government can provide basic infrastructure to its rural citizens, all those fancy malls and F16s mean little.

  • Models underestimate global warming impacts

    No, not Tyra Banks and Riyo Mori, climate models that is.

    ES&T Online News: Models underestimate global warming impacts

    Modelers don’t purposely err on the conservative side, says Marika Holland of the National Center for Atmospheric Research, but some processes “are just not well understood, and because of that have not been incorporated into climate models.” Holland has published model results on the fate of sea ice and coauthored the recent paper showing that ice is melting faster than models predicted. There are many reasons for the underestimates, she says. For example, models don’t fully capture heat transport between ocean and atmosphere, or faster warming as reflective ice gives way to darker, heat-absorbing waters.
    But Rahmstorf says that modelers might unwittingly make models more conservative by applying “one-sided filters”, weeding out models that clearly overestimate the changes seen so far, but hanging onto ones “where everything is too well behaved and stable.”

    Scientists are human too. The political and social climate in the US have been harsh to people who overestimate the effects of climate change. So, modeling scenarios that deviate significantly from accepted limits or runaway uncontrollably are discarded. Models are sets of assumptions based on underlying theory. If the theory of a particular sub-process is not clearly understood, then the assumptions become subjective. In a social climate that is waiting to pounce on an overestimate as example of negating the entire global warming phenomenon, assumptions made are conservative. This is not necessarily a bad thing, but it comes at a price! As more observations come in, it does become clear that sometimes, things are happening faster and at greater magnitudes than our model predicted.

  • Oceans of Carbon Dioxide?

    Well, possibly the biggest climate change science news of the day, sequestration with a twist. Now if we can only get those friendly little carbon dioxide molecules to march down a couple of miles down to the ocean sediments to sequester themselves! But seriously, it will take a lot of pumping.

    Permanent carbon dioxide storage in deep-sea sediments — House et al., 10.1073/pnas.0605318103 — Proceedings of the National Academy of Sciences

    Stabilizing the concentration of atmospheric CO2 may require storing enormous quantities of captured anthropogenic CO2 in near-permanent geologic reservoirs. Because of the subsurface temperature profile of terrestrial storage sites, CO2 stored in these reservoirs is buoyant. As a result, a portion of the injected CO2 can escape if the reservoir is not appropriately sealed. We show that injecting CO2 into deep-sea sediments <3,000-m water depth and a few hundred meters of sediment provides permanent geologic storage even with large geomechanical perturbations. At the high pressures and low temperatures common in deep-sea sediments, CO2 resides in its liquid phase and can be denser than the overlying pore fluid, causing the injected CO2 to be gravitationally stable. Additionally, CO2 hydrate formation will impede the flow of CO2(l) and serve as a second cap on the system. The evolution of the CO2 plume is described qualitatively from the injection to the formation of CO2 hydrates and finally to the dilution of the CO2(aq) solution by diffusion. If calcareous sediments are chosen, then the dissolution of carbonate host rock by the CO2(aq) solution will slightly increase porosity, which may cause large increases in permeability. Karst formation, however, is unlikely because total dissolution is limited to only a few percent of the rock volume. The total CO2 storage capacity within the 200-mile economic zone of the U.S. coastline is enormous, capable of storing thousands of years of current U.S. CO2 emissions.

  • James Hansen disses the Tar Sands

    James Hansen: Obama’s Canada trip defines our critical carbon moment | Comment is free | guardian.co.uk

    The tar sands of Canada constitute one of our planet’s greatest threats. They are a double-barrelled threat. First, producing oil from tar sands emits two-to-three times the global warming pollution of conventional oil. But the process also diminishes one of the best carbon-reduction tools on the planet: Canada’s Boreal Forest.

    This forest plays a key role in the global carbon equation by serving as a major storehouse for terrestrial carbon – indeed, it is believed to store more carbon per hectare than any other ecosystem on Earth. When this pristine forest is strip mined for tar sands development, much of its stored carbon is lost. Canada’s Boreal Forest is also the reservoir for a large fraction of North America’s clean, fresh water, home to some five billion migratory birds, and some of largest remaining populations of caribou, moose, bear and wolves on the planet.

    Nothing more to say, except that he does a good job of connecting both the inefficiency of the extraction process, a carbon source, and the destruction of the boreal forest, the removal of a carbon sink. If carbon accounting was in place, the economics would not work. Harper knows this, hence all the aggressive PR to get ahead of the game.

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    Snake Oil Comes a Full Circle

    Ah, back to the good old days of snake oil..

    ScienceDaily: Snake Venom As Therapeutic Treatment Of Cancer?

    This certainly sounds unusual, but Dr. Son and colleagues report on the effectiveness of the snake venom toxin (SVT) Vipera lebetina turanica in the inhibition of androgen-independent prostate cancer (AICAP) in the journal Molecular Cancer Therapeutics.

    These novel findings suggest that SVT can inhibit the growth of AICAP through the induction of cell death.

    I am glad they put the question mark at the end, lest people extrapolate from a few cells in a petri dish (or a small animal study) to a cancer cure, as happened recently with dichloroacetate! Health reporting is very tricky because the average reader cannot understand much more than the headline. It almost seems like every health article should have the following things clearly labeled:

    1. Human, animal or cell?
    2. Clinically tested, or anecdotal?
    3. Double blinded, controlled, etc, or not?
    4. Any chance that this result applies to people?
    5. How far away are we from a real cure?
    6. DO NOT TRY THIS AT HOME!

    At least viper venom is hard to find! The Madras crocodile bank helped start a venom extraction cooperative run by the Irula Tribe, so I’ve seen viper venom being extracted, pretty cool. India is home to two vipers, the Russell’s and the Saw Scaled vipers.

    Russell's
    Russell’s viper

    saw scaled
    Saw scaled viper.

    The Russell’s is 3-5 feet long, and slow, but a big hisser! The saw scaled viper is tiny, a feet or two, but aggressive and very venomous. One of my favorite wild snake sightings was a saw scaled viper, looked very innocuous curled up in a parking lot in Pondicherry.

    Cool, snake oil and venom for all…

  • Canada – No new coal plants?

    For a minute I thought the pain from playing volleyball last night, plus opening my computer up sleepily at 5:45 in the morning before catching an early bus to work had me hallucinating, but yes, the Canadian federal government actually wants to impose a moratorium on the construction of new coal fired power plants unless they include sequestration (which to me means no new power plants).

    The federal government is planning sweeping new climate-change regulations for Canada's electricity sector that will phase out traditional coal-fired power

    Any new coal plants will have to include highly expensive – and unproven – technology to capture greenhouse gas emissions and inject it underground for permanent storage, Environment Minister Jim Prentice said in an interview yesterday.

    Ottawa also plans to impose absolute emission caps on utilities' existing coal-fired power plants and establish a market-based system to allow them to buy credits to meet those targets, Mr. Prentice said.

    via reportonbusiness.com: Ottawa takes aim at coal power.

    I have a certain distrust for this government, so details are crucial. The right things are being said:

    1. All new plants will need sequestration
    2. A cap and trade to deal with existing coal fired power plants
    3. Phase out of facilities after “fully amortized life” – Not clear on exactly what that means
    4. 90% Emissions free power sector by 2025

    As the article points out, Canada relies on coal much less than a lot of other countries, only 18% of current emissions are from coal, as opposed to the US, where about 40% is from coal.

    So, time to celebrate? Not exactly. Canada’s latest release of 2007 data indicates horrendous performance.

    Canada 2007 GHG Inventory

    Overall, total increase was 6 Megatonnes from 2004 to 2007. But the increases from the Tar Sands were nearly 16 Mt, meaning most of Canada’s other sectors saw decreases, thanks to a number of mild winters and greater efficiency.

    Clearly, this performance is going to continue until the Tar Sands are included in any CO2 reduction strategies, whatever we do, or don’t do with the coal will have a little bit of impact, but will definitely not help Canada achieve any of its short or long term goals.

    So, one cheer for this announcement. I suspect that the administration needs something to take to meetings, and is hoping that a coal moratorium will distract people from the biggest culprits, the Tar Sands and our insanely high per capita GHG footprint. A “no new coal” moratorium would be a huge deal in the States, and off the charts in China or India as far as reducing emissions go. But Canada, not bad, but definitely not good enough!

    The Tar Sands will only be stopped when the US steps up to the plate and gets its Cap and Trade going.